Callyspongamide A, a new cytotoxic polyacetylenic amide from the Red Sea sponge Callyspongia fistularis

J Nat Prod. 2003 Jun;66(6):861-2. doi: 10.1021/np0205809.

Abstract

Callyspongamide A (1), a new cytotoxic polyacetylenic amide, has been isolated from the marine sponge Callyspongia fistularis collected in the Red Sea. Callyspongamide A is an amide derivative of a C(17)-polyacetylenic acid and phenethylamine. It represents a new class of secondary metabolites within the family Callyspongiidae. Its structure was determined on the basis of 1D and 2D (COSY, HOHAHA, HMQC, and HMBC) NMR studies and high-resolution mass spectral measurement.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetylene / analogs & derivatives
  • Acetylene / chemistry
  • Acetylene / isolation & purification*
  • Acetylene / pharmacology
  • Alkynes
  • Amides / chemistry
  • Amides / isolation & purification*
  • Amides / pharmacology
  • Animals
  • Antineoplastic Agents / chemistry
  • Antineoplastic Agents / isolation & purification*
  • Antineoplastic Agents / pharmacology
  • Drug Screening Assays, Antitumor
  • HeLa Cells / drug effects
  • Humans
  • Indian Ocean
  • Molecular Structure
  • Nuclear Magnetic Resonance, Biomolecular
  • Polymers / chemistry
  • Polymers / isolation & purification*
  • Polymers / pharmacology
  • Porifera / chemistry*
  • Tumor Cells, Cultured / drug effects

Substances

  • Alkynes
  • Amides
  • Antineoplastic Agents
  • Polymers
  • callyspongamide A
  • Acetylene