Shear-flow-based chromatographic separations as an alternative to pressure-driven liquid chromatography

J Chromatogr A. 2002 Mar 1;948(1-2):19-34. doi: 10.1016/s0021-9673(01)01511-4.

Abstract

It is only by developing specially designed injection and detection systems that shear-driven chromatography can become a viable alternative to HPLC. In the present paper, a dedicated zero dead-volume injection procedure is presented with which sample volumes can be injected reproducibly in the required picoliter range. In addition, a transversal detection groove system is designed which should allow to perform on-line UV-VIS absorption measurements with path lengths in the millimeter range, with an acceptable theoretical plate loss (only 20% in a 5 cm long channel) and acting as a nearly perfect wave guide.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Algorithms
  • Chemical Phenomena
  • Chemistry, Physical
  • Chromatography, High Pressure Liquid / instrumentation*
  • Chromatography, High Pressure Liquid / methods
  • Chromatography, Liquid / instrumentation*
  • Chromatography, Liquid / methods
  • Diffusion
  • Spectrophotometry, Ultraviolet