Abstract
Chemical structural elucidation of epoxyrollins A and B, representatives of biosynthetic precursors of tetrahydrofuran and tetrahydropyran annonaceous acetogenins, is described. These chemical structures were diepoxyreticanin 1 (4) and diepoxymuricanin A (6) by a (13)C-NMR and mass spectral study of the natural and synthetic sample data.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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4-Butyrolactone / analogs & derivatives
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4-Butyrolactone / chemistry*
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Annonaceae / chemistry*
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Electron Transport Complex I / antagonists & inhibitors
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Enzyme Inhibitors / chemistry
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Epoxy Compounds / chemistry*
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Mass Spectrometry
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Molecular Structure
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Multienzyme Complexes / antagonists & inhibitors
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NADH, NADPH Oxidoreductases / antagonists & inhibitors
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Nuclear Magnetic Resonance, Biomolecular
Substances
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Enzyme Inhibitors
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Epoxy Compounds
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Multienzyme Complexes
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epoxyrollin A
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epoxyrollin B
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NADH oxidase
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NADH, NADPH Oxidoreductases
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Electron Transport Complex I
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4-Butyrolactone