An enantioselective double Diels-Alder approach to the tetracyclic framework of colombiasin A

Jason H Chaplin; Alison J Edwards; Bernard L Flynn

doi:10.1039/b302522e

An enantioselective double Diels-Alder approach to the tetracyclic framework of colombiasin A

Org Biomol Chem. 2003 Jun 7;1(11):1842-4. doi: 10.1039/b302522e.

Authors

Jason H Chaplin¹, Alison J Edwards, Bernard L Flynn

Affiliation

¹ Department of Chemistry, The Faculties, Australian National University, Canberra, ACT 0200, Australia.

PMID: 12945762
DOI: 10.1039/b302522e

Abstract

The complex tetracyclic carbon skeleton of colombiasin A is conveniently accessed through an enantioselective intermolecular Diels-Alder-sulfoxide elimination-intramolecular Diels-Alder (DA-E-IMDA) sequence.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Bridged-Ring Compounds / chemical synthesis*
Bridged-Ring Compounds / chemistry
Molecular Structure
Stereoisomerism
Sulfoxides / chemistry

Substances

Bridged-Ring Compounds
Sulfoxides
colombiasin A