Phosphorylation of tyrosine 393 in the kinase domain of Bcr-Abl influences the sensitivity towards imatinib in vivo

Leukemia. 2003 Sep;17(9):1695-9. doi: 10.1038/sj.leu.2403040.

Abstract

The Bcr-Abl fusion protein arising through the t(9;22)(q34;q11) reciprocal translocation is the causative agent in chronic myeloid leukemia and a subset of acute lymphocytic leukemia. Imatinib mesylate is a specific inhibitor of the Bcr-Abl kinase and has shown promising results in clinical studies. The structural relation between the Bcr-Abl oncogene and the tyrosine kinase inhibitor imatinib has recently been elucidated by an elegant crystal structure analysis, emphasizing the importance of dephosphorylated tyrosine 393 (Tyr393) in Bcr-Abl for access of the inhibitor to the kinase domain. By mutating this tyrosine to phenylalanine and thereby mimicking a constitutively dephosphorylated state, we now show that Ba/F3 cells transformed by this mutant demonstrate an increased sensitivity towards imatinib in vivo. This effect is not due to an impaired kinase activity of Bcr-Abl Y393F, since a synthetic substrate is phosphorylated with similar kinetics. Treatment of Ba/F3 cells transfected with Bcr-Abl wild type with a phosphatase inhibitor diminished the effect of imatinib, but did not influence the growth of Ba/F3 cells transfected with Bcr-AblY393F. The results support the findings of the crystal structure and indicate that Tyr393 indeed plays a significant role for the sensitivity of Bcr-Abl towards imatinib in vivo. These data implicate the regulation of Tyr393 phosphorylation as a potential mechanism of imatinib resistance.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Antineoplastic Agents / therapeutic use*
  • Benzamides
  • Cell Division / drug effects
  • Cell Line / drug effects
  • DNA-Binding Proteins / metabolism
  • Fusion Proteins, bcr-abl / metabolism*
  • Gene Expression Regulation, Neoplastic
  • Humans
  • Imatinib Mesylate
  • Leukemia, Myelogenous, Chronic, BCR-ABL Positive / drug therapy*
  • Leukemia, Myelogenous, Chronic, BCR-ABL Positive / metabolism
  • Milk Proteins*
  • Mutagenesis, Site-Directed
  • Mutation / genetics
  • Phosphorylation
  • Piperazines / therapeutic use*
  • Pyrimidines / therapeutic use*
  • STAT5 Transcription Factor
  • Trans-Activators / metabolism
  • Transfection
  • Tyrosine / metabolism*

Substances

  • Antineoplastic Agents
  • Benzamides
  • DNA-Binding Proteins
  • Milk Proteins
  • Piperazines
  • Pyrimidines
  • STAT5 Transcription Factor
  • Trans-Activators
  • Tyrosine
  • Imatinib Mesylate
  • Fusion Proteins, bcr-abl