Identification of a sequence within the C-terminal 26 amino acids of cholesteryl ester transfer protein responsible for binding a neutralizing monoclonal antibody and necessary for neutral lipid transfer activity

J Biol Chem. 1992 Sep 5;267(25):17487-90.

Abstract

The cholesteryl ester transfer protein (CETP; 476 amino acids) mediates the transfer of neutral lipids and phospholipids between plasma lipoproteins. Previous studies showed that the epitope of a neutralizing monoclonal antibody (TP2) was located within the C-terminal 26 amino acids (aa) of CETP. To determine possible involvement of this region in lipid transfer activities, we generated six deletion mutants between Arg-451 and Leu-475 by in vitro mutagenesis and expressed mutant proteins in mammalian cells. Only deletion mutants between aa Phe-463 and Leu-475 failed to bind TP2; these mutant proteins were well secreted by cells but showed markedly reduced cholesteryl ester transfer activity. One of the deletion mutants (delta 470-475) showed similar reductions in cholesteryl ester and triglyceride transfer activities but normal or increased phospholipid transfer activity. Limited proteolysis of this mutant protein indicated a similar overall folding pattern to the wild-type protein. Thus, aa between Phe-463 and Leu-475 are necessary for binding TP2. Deletions within this sequence selectively impair neutral lipid transfer activity, suggesting a direct involvement in neutral lipid transfer.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Antibodies, Monoclonal
  • CHO Cells
  • Carrier Proteins / genetics
  • Carrier Proteins / immunology
  • Carrier Proteins / metabolism*
  • Cell Line
  • Cholesterol Ester Transfer Proteins
  • Cholesterol Esters / metabolism*
  • Chromosome Deletion
  • Cricetinae
  • Epitopes / analysis*
  • Glycoproteins*
  • Kinetics
  • Molecular Sequence Data
  • Mutagenesis, Site-Directed
  • Neutralization Tests
  • Peptide Fragments / isolation & purification
  • Phospholipids / metabolism
  • Recombinant Proteins / immunology
  • Recombinant Proteins / metabolism
  • Substrate Specificity
  • Transfection

Substances

  • Antibodies, Monoclonal
  • Carrier Proteins
  • Cholesterol Ester Transfer Proteins
  • Cholesterol Esters
  • Epitopes
  • Glycoproteins
  • Peptide Fragments
  • Phospholipids
  • Recombinant Proteins