New glycosphingolipids from the marine sponge Halichondria panicea

J Nat Prod. 1992 Jul;55(7):1013-7. doi: 10.1021/np50085a032.

Abstract

A novel sphingolipid containing an iso-fatty acid, (4E,8E)-N-13'-methyltetradecanoyl-1-O-beta-D-glucopyra nosyl-4-sphingadiene, was isolated from the Oregon marine sponge Halichondria panicea and its structure determined using a combination of spectroscopic and chemical degradation techniques. A second galactosyl-ceramide, which contained an unusually long chain fatty acid amide component, was also isolated from H. panicea.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Animals
  • Glycosphingolipids / chemistry
  • Glycosphingolipids / isolation & purification*
  • Molecular Conformation
  • Molecular Structure
  • Optical Rotation
  • Porifera / chemistry*

Substances

  • Glycosphingolipids