[The application of circular dichroism on the structure analysis of natural products--diterpenoid dilactones and tylophorines]

Yao Xue Xue Bao. 1992;27(3):197-203.
[Article in Chinese]

Abstract

In this paper, circular dichroism (CD), sector projection and reverse octant rule projection of four diterpenoid dilactones and five tylophorines (two of them, 6, 8, are new compounds) are reported in which reverse octant rule projection is the first application to the configuration determination of diterpenoid dilactone. By using these rules, the predicted Cotton effects of these compounds coincided with the result of previous determinations, so, their absolute configurations are assigned.

Publication types

  • English Abstract

MeSH terms

  • Alkaloids*
  • Circular Dichroism
  • Diterpenes / chemistry*
  • Diterpenes / isolation & purification
  • Drugs, Chinese Herbal / chemistry
  • Indolizines / chemistry*
  • Indolizines / isolation & purification
  • Lactones / chemistry*
  • Lactones / isolation & purification
  • Molecular Conformation
  • Phenanthrenes*

Substances

  • Alkaloids
  • Diterpenes
  • Drugs, Chinese Herbal
  • Indolizines
  • Lactones
  • Phenanthrenes
  • tylophorine