The first structurally characterised perchlorato-cobalt(III) complexes, involving the C-bonded macrobicyclic ligand 1,4,8,11-tetraazabicyclo[9.5.2]octadecane

Xiangting Zhou; Anthony I Day; Anthony C Willis; W Gregory Jackson

doi:10.1039/b305182j

The first structurally characterised perchlorato-cobalt(III) complexes, involving the C-bonded macrobicyclic ligand 1,4,8,11-tetraazabicyclo[9.5.2]octadecane

Chem Commun (Camb). 2003 Sep 21:(18):2386-7. doi: 10.1039/b305182j.

Authors

Xiangting Zhou¹, Anthony I Day, Anthony C Willis, W Gregory Jackson

Affiliation

¹ School of Chemistry, University College, The University of New South Wales, Australian Defence Force Academy, Canberra ACT 2600, Australia.

PMID: 14518927
DOI: 10.1039/b305182j

Abstract

Two isomeric C-bonded complexes, sym-anti-[Co(L-C)(OH2)]2+ and sym-syn-[Co(L-C)(OH2)]2+ (L = 1,4,8,11-tetraazabicyclo[9.5.2]octadecane) when crystallised from aqueous NaClO4 remarkably yielded the corresponding perchlorato complexes, confirmed by the single crystal X-ray structures.