New antimicrobial cystatin C-based peptide active against gram-positive bacterial pathogens, including methicillin-resistant Staphylococcus aureus and multiresistant coagulase-negative staphylococci

APMIS. 2003 Nov;111(11):1004-10. doi: 10.1111/j.1600-0463.2003.t01-1-apm1111110.x.

Abstract

We describe the synthesis and antibacterial properties of a novel antimicrobial peptidyl derivative, (2S)-2-(Nalpha-benzyloxycarbonyl-arginyl-leucylamido-1-[(E)-cinnamoylamido]-3-methylbutane, structurally based upon the inhibitory centre of the human cysteine protease inhibitor, cystatin C. The derivative, here called Cystapep 1, displayed antibacterial activity against several clinically important gram-positive bacteria. It displayed minimal inhibitory and bactericidal concentrations of about 16 microg/ml for both Staphylococcus aureus and Streptococcus pyogenes. In radial agar diffusion assays, groups A, B, C and G streptococci as well as staphylococci were generally susceptible to the action of Cystapep 1, whereas pneumococci and enterococci were less susceptible. No activity against gram-negative bacteria was observed. Cystapep 1 also showed high activity against methicillin-resistant S. aureus (MRSA) and multiantibiotic-resistant coagulase-negative staphylococci (CNS), suggesting that its mechanism of action differs from those of most currently used antibiotics.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Anti-Bacterial Agents / chemical synthesis
  • Anti-Bacterial Agents / pharmacology*
  • Cystatin C
  • Cystatins / chemistry
  • Dipeptides / chemical synthesis
  • Dipeptides / pharmacology*
  • Drug Resistance, Multiple, Bacterial
  • Gram-Positive Cocci / drug effects*
  • Humans
  • Methicillin Resistance
  • Microbial Sensitivity Tests
  • Oligopeptides / chemical synthesis
  • Oligopeptides / pharmacology
  • Staphylococcus aureus / drug effects
  • Streptococcus pyogenes / drug effects

Substances

  • 2-(N(alpha)-benzyloxycarbonyl-arginyl-leucylamido)-1-(cinnamoylamido)-3-methylbutane
  • Anti-Bacterial Agents
  • CST3 protein, human
  • Cystatin C
  • Cystatins
  • Dipeptides
  • Oligopeptides