Activation of the Raf-1/MEK/Erk kinase pathway by a novel Cdc25 inhibitor in human prostate cancer cells

Prostate. 2004 Jan 1;58(1):95-102. doi: 10.1002/pros.10292.

Abstract

Background: The serine/threonine kinase Raf-1 is a major regulator of the mitogen activated protein kinase (MAPK) pathway, which has been associated with the progression of prostate cancer to the more advanced and androgen-independent disease. Cdc25A phosphatase has been implicated in the regulation of Raf-1 and the MAPK pathway.

Methods: We used a novel and potent Cdc25A inhibitor, 2,3-bis-[2-hydroxyethylsulfonyl]-[1,4] naphthoquinone (NSC 95397), and its congener (2-mercaptoethanol)-3-methyl-1, 4-naphthoquinone (NSC 672121) to study the role of Cdc25A on the MAPK pathway in human prostate cancer cells.

Results: We found Raf-1 physically interacted with Cdc25A in PC-3 and LNCap cells and inhibitors of Cdc25A induced both extracellular signal-regulated kinase (Erk) activation and Raf-1 tyrosine phosphorylation. NSC 95397 attenuated Cdc25A and Raf-1 interactions due to accelerated degradation of Cdc25A, which was mediated by proteasome degradation. The MAPK kinase (MEK) inhibitor U0126 completely inhibited Erk activation by NSC 95397 and NSC 672121.

Conclusions: These results indicate Cdc25A phosphatase regulates Raf-1/MEK/Erk kinase activation in human prostate cancer cells.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Blotting, Western
  • Butadienes / pharmacology
  • Cell Line, Tumor
  • Enzyme Inhibitors / pharmacology*
  • Humans
  • Leupeptins / pharmacology
  • MAP Kinase Signaling System / drug effects*
  • Male
  • Mitogen-Activated Protein Kinases / metabolism*
  • Naphthoquinones / pharmacology
  • Nitriles / pharmacology
  • Phosphorylation
  • Prostatic Neoplasms / enzymology*
  • Proto-Oncogene Proteins c-raf / metabolism*
  • cdc25 Phosphatases / antagonists & inhibitors*
  • cdc25 Phosphatases / metabolism

Substances

  • 2,3-bis(2-hydroxyethylsulfanyl)-(1,4)naphthoquinone
  • Butadienes
  • Enzyme Inhibitors
  • Leupeptins
  • Naphthoquinones
  • Nitriles
  • U 0126
  • Proto-Oncogene Proteins c-raf
  • Mitogen-Activated Protein Kinases
  • CDC25A protein, human
  • cdc25 Phosphatases
  • benzyloxycarbonylleucyl-leucyl-leucine aldehyde