Structure and magnetism of a new pyrazolate bridged iron(II) spin crossover complex displaying a single HS-HS to LS-LS transition

Ben A Leita; Boujemaa Moubaraki; Keith S Murray; Jonathan P Smith; John D Cashion

doi:10.1039/b311818e

Structure and magnetism of a new pyrazolate bridged iron(II) spin crossover complex displaying a single HS-HS to LS-LS transition

Chem Commun (Camb). 2004 Jan 21:(2):156-7. doi: 10.1039/b311818e. Epub 2003 Nov 20.

Authors

Ben A Leita¹, Boujemaa Moubaraki, Keith S Murray, Jonathan P Smith, John D Cashion

Affiliation

¹ School of Chemistry, Monash University, P.O Box 23, Clayton, Victoria, Australia.

PMID: 14737526
DOI: 10.1039/b311818e

Abstract

The dinuclear iron(II) complex [(pypzH)(NCSe)Fe([micro sign]-pypz)(2)Fe(NCSe)(pypzH)].2H(2)O displays a single, sharp spin crossover transition between the [HS-HS] and [LS-LS] states and is structurally characterised above and below the T(1/2)= 225 K value