Slow magnetic relaxation in a mixed-valence Mn(II/III) Complex: [MnII2(bispicen)2(mu 3-Cl)2Mn(III)(Cl4Cat)2Mn(III)(Cl4Cat)2(H2O)2] infinity

Nizamuddin Shaikh; Anangamohan Panja; Sanchita Goswami; Pradyot Banerjee; Pavel Vojtísek; Yuan-Zhu Zhang; Gang Su; Song Gao

doi:10.1021/ic035072g

Slow magnetic relaxation in a mixed-valence Mn(II/III) Complex: [MnII2(bispicen)2(mu 3-Cl)2Mn(III)(Cl4Cat)2Mn(III)(Cl4Cat)2(H2O)2] infinity

Inorg Chem. 2004 Feb 9;43(3):849-51. doi: 10.1021/ic035072g.

Authors

Nizamuddin Shaikh¹, Anangamohan Panja, Sanchita Goswami, Pradyot Banerjee, Pavel Vojtísek, Yuan-Zhu Zhang, Gang Su, Song Gao

Affiliation

¹ Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Kolkata 700 032, India.

PMID: 14753802
DOI: 10.1021/ic035072g

Abstract

A layered mixed-valence manganese complex, [Mn(II)(2)(bispicen)(2)(mu(3)-Cl)(2)Mn(III)(Cl(4)Cat)(2)Mn(III)(Cl(4)Cat)(2)(H(2)O)(2)](infinity), is synthesized and characterized structurally. It displays a slow magnetic relaxation and hysteresis effect.