Abstract
The hydrozirconation of alkynes with zirconocene hydrochloride and the dimethylzinc-mediated addition of alkenylzirconocenes to diphenylphosphinoyl imines can be greatly accelerated with microwave irradiation, resulting in a convenient and rapid one-pot process for the preparation of synthetically useful allylic amines.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Allyl Compounds / chemical synthesis*
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Amines / chemical synthesis*
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Hydrogen / chemistry*
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Imines / chemistry*
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Microwaves
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Molecular Structure
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Silicates / chemistry*
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Zirconium / chemistry*
Substances
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Allyl Compounds
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Amines
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Imines
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Silicates
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zircon
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Hydrogen
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Zirconium