(1E)-2-(Diacetylamino)-1-methylprop-1-enyl acetate

Acta Crystallogr C. 2004 Mar;60(Pt 3):o196-7. doi: 10.1107/S0108270104000332. Epub 2004 Feb 10.

Abstract

The analysis of the title compound, C10H15NO4, firmly establishes the configuration of the double bond as E, a stereochemistry that had been assigned tentatively by other methods. The diacetylamine and acetate substituents are approximately coplanar to one another, but approximately perpendicular to the planar ethene core. H atoms of the ethene methyl substituents are found within the ethene plane, indicating that hyperconjugation does not play an important role in stabilizing the double bond.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetates / chemistry*
  • Alanine / analogs & derivatives*
  • Crystallography, X-Ray
  • Molecular Structure
  • Pyridines / chemistry
  • Stereoisomerism

Substances

  • 2-(diacetylamino)-1-methylprop-1-enyl acetate
  • Acetates
  • Pyridines
  • pyridine
  • Alanine