Synthesis and structure of heterospin compounds based on the [Mn6(O)2Piv10]-cluster unit and nitroxide

Victor Ovcharenko; Elena Fursova; Galina Romanenko; Vladimir Ikorskii

doi:10.1021/ic049859y

Synthesis and structure of heterospin compounds based on the [Mn6(O)2Piv10]-cluster unit and nitroxide

Inorg Chem. 2004 May 31;43(11):3332-4. doi: 10.1021/ic049859y.

Authors

Victor Ovcharenko¹, Elena Fursova, Galina Romanenko, Vladimir Ikorskii

Affiliation

¹ International Tomography Center SB RAS, 630090 Novosibirsk, Russia. [email protected]

PMID: 15154792
DOI: 10.1021/ic049859y

Abstract

Reaction of [Mn6(O)2Piv10(Thf)4].Thf with 2,4,4,5,5-pentamethyl-4,5-dihydro-1H-imidazolyl-3-oxide-1-oxyl (NIT-Me) produces different heterospin compounds depending of the solvent used in the synthesis. Among the latter a new molecular magnet [Mn6(O)2Piv10(Thf)2(NIT-Me)Mn6(O)2Piv10(Thf)(CH2Cl2)(NIT-Me)] with Tc = 3.5 K has been found.