Use and optimization of a dual-flowrate loading strategy to maximize throughput in protein-a affinity chromatography

Biotechnol Prog. 2004 May-Jun;20(3):830-40. doi: 10.1021/bp0342654.

Abstract

The effect of an alternate strategy employing two different flowrates during loading was explored as a means of increasing system productivity in Protein-A chromatography. The effect of such a loading strategy was evaluated using a chromatographic model that was able to accurately predict experimental breakthrough curves for this Protein-A system. A gradient-based optimization routine is carried out to establish the optimal loading conditions (initial and final flowrates and switching time). The two-step loading strategy (using a higher flowrate during the initial stages followed by a lower flowrate) was evaluated for an Fc-fusion protein and was found to result in significant improvements in process throughput. In an extension of this optimization routine, dynamic loading capacity and productivity were simultaneously optimized using a weighted objective function, and this result was compared to that obtained with the single flowrate. Again, the dual-flowrate strategy was found to be superior.

Publication types

  • Comparative Study
  • Evaluation Study
  • Validation Study

MeSH terms

  • Adsorption
  • Animals
  • Antibodies, Monoclonal / chemistry
  • Antibodies, Monoclonal / genetics
  • Antibodies, Monoclonal / immunology
  • Antibodies, Monoclonal / isolation & purification
  • Antigen-Antibody Complex / chemistry
  • Antigen-Antibody Complex / immunology
  • Antigen-Antibody Complex / isolation & purification
  • CHO Cells
  • Chromatography, Affinity / methods*
  • Complex Mixtures / chemistry
  • Complex Mixtures / immunology
  • Complex Mixtures / isolation & purification
  • Computer Simulation
  • Cricetinae
  • Cricetulus
  • Culture Media / chemistry
  • Culture Media / isolation & purification
  • Immunoglobulin Fc Fragments / chemistry*
  • Immunoglobulin Fc Fragments / genetics
  • Immunoglobulin Fc Fragments / immunology
  • Immunoglobulin Fc Fragments / isolation & purification*
  • Microfluidics / methods*
  • Models, Chemical*
  • Quality Control
  • Recombinant Fusion Proteins / chemistry
  • Recombinant Fusion Proteins / immunology
  • Recombinant Fusion Proteins / isolation & purification
  • Staphylococcal Protein A / chemistry*
  • Staphylococcal Protein A / immunology
  • Staphylococcal Protein A / isolation & purification*

Substances

  • Antibodies, Monoclonal
  • Antigen-Antibody Complex
  • Complex Mixtures
  • Culture Media
  • Immunoglobulin Fc Fragments
  • Recombinant Fusion Proteins
  • Staphylococcal Protein A