Purpurinimide-fullerene dyads: introduction of fullerene moiety at various peripheral positions of the purpurinimide system

Org Lett. 2004 Jul 8;6(14):2393-6. doi: 10.1021/ol0492290.

Abstract

[reaction: see text] Fullerene was regioselectively introduced at various peripheral positions of N-hexyl-purpurinimide for photoinduced electron transfer studies. Remarkably different effects of the position of the fullerene moiety in the formation of atropisomers were observed.

Publication types

  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Amino Acids / chemical synthesis
  • Catalysis
  • Fullerenes / chemistry*
  • Glycine / chemistry
  • Indicators and Reagents
  • Lactams / chemical synthesis
  • Models, Molecular
  • Molecular Structure
  • Stereoisomerism
  • Tartrates / chemistry*

Substances

  • Amino Acids
  • Fullerenes
  • Indicators and Reagents
  • Lactams
  • Tartrates
  • streptolidine
  • Glycine