Highly symmetric networks derived from cubane-related octametallic complexes of a new oxyanion of carbon, C4O7(4-), each molecule attached to eight neighbors by 24 equivalent hydrogen bonds

Brendan F Abrahams; Timothy A Hudson; Richard Robson

doi:10.1021/ja048293+

Highly symmetric networks derived from cubane-related octametallic complexes of a new oxyanion of carbon, C4O7(4-), each molecule attached to eight neighbors by 24 equivalent hydrogen bonds

J Am Chem Soc. 2004 Jul 21;126(28):8624-5. doi: 10.1021/ja048293+.

Authors

Brendan F Abrahams¹, Timothy A Hudson, Richard Robson

Affiliation

¹ Contribution from the School of Chemistry, University of Melbourne, Victoria 3010, Australia.

PMID: 15250694
DOI: 10.1021/ja048293+

Abstract

Aqueous reaction mixtures containing dihydroxyfumaric acid, M2+ (M = Zn, Co, Fe, and Mg) and acetate ion at room temperature give crystals, suitable for single-crystal X-ray diffraction studies, of composition [(MII)8(C4O7)4(H2O)12].24H2O, in which the C4O74- component is the alkoxide-tricarboxylate tetra-anionic species -OC(CO2-)3, a new oxyanion of carbon. All four compounds crystallize in the body-centered space group I3m with cell dimensions a approximately 15.0 A. Discrete electrically neutral [(MII)8(C4O7)4(H2O)12] molecules are present, with a cubane-like core consisting of four trigonal prismatic metal centers and four mu3-alkoxo bridges from separate -OC(CO2-)3 ligands. The octametallic molecule is highly symmetrical, with four fac tri-aqua octahedral metal centers tetrahedrally appended to the central cubane-based [(MII)8(C4O7)4 ]8- unit. The molecules assemble in the crystal in a body-centered cubic fashion, each being attached to its eight neighbors by 24 equivalent hydrogen bonds-an extreme example of self-complementarity.