Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes

Dalton Trans. 2004 Feb 7:(3):354-6. doi: 10.1039/b314027j. Epub 2004 Jan 14.

Abstract

The eta1-hydroxylamido half-titanocene complex, CpTiCl2(TEMPO) 1, hydrolyzes extremely efficiently to generate (CpTiClO)4 and the protonated hydroxylamine. The efficient hydrolysis chemistry provides selective syntheses of CpTi dialkoxide and diaryloxide complexes.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cyclic N-Oxides / chemistry
  • Cyclopentanes / chemistry
  • Hydrolysis
  • Molecular Structure
  • Organometallic Compounds* / chemical synthesis
  • Organometallic Compounds* / chemistry
  • Titanium / chemistry*

Substances

  • Cyclic N-Oxides
  • Cyclopentanes
  • Organometallic Compounds
  • Titanium
  • TEMPO