The observation of superparamagnetic behavior in molecular nanowires

Shi Wang; Jing-Lin Zuo; Song Gao; You Song; Hong-Cai Zhou; Yuan-Zhu Zhang; Xiao-Zeng You

doi:10.1021/ja0483995

The observation of superparamagnetic behavior in molecular nanowires

J Am Chem Soc. 2004 Jul 28;126(29):8900-1. doi: 10.1021/ja0483995.

Authors

Shi Wang¹, Jing-Lin Zuo, Song Gao, You Song, Hong-Cai Zhou, Yuan-Zhu Zhang, Xiao-Zeng You

Affiliation

¹ Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China.

PMID: 15264813
DOI: 10.1021/ja0483995

Abstract

Using the anionic precursor [(Tp)Fe(CN)3]-, a new one-dimensional Ising cyanide-bridged chain, [(Tp)2FeIII2(CN)6Cu(CH3OH).2CH3OH]n, has been prepared. The crystal structure and magnetic studies demonstrate that it is a single-chain magnet and the blocking temperature is ca. 6 K.