Ab initio calculations on the six-dimensional cis--trans double minimum potential energy surface of the electronic ground state of the HONO molecule were performed using a coupled cluster approach. An analytic fit to the data points was established. The interconversion barrier was calculated to be 4105 cm(-1). The nuclear motion problem was solved variationally using a full six-dimensional Hamiltonian in internal coordinates. The eigenstates up to about 3650 cm(-1) were tentatively assigned by harmonic quantum numbers. The assignment was based on the mean values of the internal coordinates of the six-dimensional eigenfunctions and on a comparison of the eigenenergies with those calculated by second-order perturbation theory from a full quartic force field in dimensionless normal coordinates. In cold matrices the trans- and the cis-OH nu(1) stretching modes and the first trans- and cis-NO 2nu(2) stretching overtones lead to isomerization. In the isolated molecule these modes (J=0) were found to be entirely localized. However, several overtones of the nu(4) ONO bending and nu(5) N-O stretching, which are close in energy to the OH stretch and combined with the torsional mode, were found to be strongly cis-trans delocalized.