Molecular dynamics of glucose in solution: a quasielastic neutron scattering study

J Chem Phys. 2004 Feb 22;120(8):3527-30. doi: 10.1063/1.1648302.

Abstract

The molecular dynamics of glucose dissolved in heavy water have been investigated at 280 K by the technique of quasielastic neutron scattering. The scattering was described by a dynamic structure factor that accounts for decoupled diffusive jumps and free rotational motions of the glucose molecules. With increasing glucose concentration, the diffusion constant decreases by a factor five and the time between jumps increases considerably. Our observations validate theoretical predictions concerning the impact of concentration on the environment of a glucose molecule and the formation of cages made by neighboring glucose molecules at higher concentrations.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Diffusion
  • Energy Transfer
  • Glucose / chemistry*
  • Molecular Conformation
  • Neutrons*
  • Rotation
  • Scattering, Radiation
  • Temperature

Substances

  • Glucose