Engineering the thermostability of Trichoderma reesei endo-1,4-beta-xylanase II by combination of disulphide bridges

Extremophiles. 2004 Oct;8(5):393-400. doi: 10.1007/s00792-004-0400-9. Epub 2004 Jul 20.

Abstract

Disulphide bridges were introduced in different combinations into the N-terminal region and the single alpha-helix of mesophilic Trichoderma reesei xylanase II (TRX II). We used earlier disulphide-bridge data and designed new disulphide bridges for the combination mutants. The most stable mutant contained two disulphide bridges (between positions 2 and 28 and between positions 110 and 154, respectively) and the mutations N11D, N38E, and Q162H. With a half-life of approximately 56 h at 65 degrees C, the thermostability of this sevenfold mutant was approximately 5,000 times higher than that of TRX II, and the half-life was 25 min even at 75 degrees C. The thermostability of this mutant was approximately 30 times higher than that of the corresponding mutant missing the bridge between positions 2 and 28. The extensive stabilization at two protein regions did not alter the kinetic properties of the sevenfold mutant from that of the wild-type TRX II. The combination of disulphide bridges enhanced significantly the pH-dependent stability in a wide pH range.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Disulfides / chemistry
  • Endo-1,4-beta Xylanases / chemistry*
  • Enzyme Stability
  • Hot Temperature
  • Hydrogen-Ion Concentration
  • Kinetics
  • Models, Molecular
  • Mutation
  • Protein Conformation
  • Protein Engineering / methods*
  • Protein Structure, Secondary
  • Temperature
  • Time Factors
  • Trichoderma / enzymology*
  • Trichoderma / genetics

Substances

  • Disulfides
  • Endo-1,4-beta Xylanases