Semiconductor-encapsulated peptide-amphiphile nanofibers

J Am Chem Soc. 2004 Oct 13;126(40):12756-7. doi: 10.1021/ja0499344.

Abstract

We report here on the use of peptide-amphiphile (PA) nanofibers displaying the S(P)RGD peptide sequence on their exterior as templates for the mineralization of cadmium sulfide (CdS). At low Cd:PA ratios, the nanofibers nucleate and organize quantum-confined 3-5 nm CdS nanocrystals into linear arrays. Tubular structures, in which the PA fibers are completely encapsulated by the semiconductor, are produced at higher Cd:PA ratios.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Cadmium Compounds / chemistry*
  • Hydrogen-Ion Concentration
  • Hydroxyapatites / chemistry
  • Microscopy, Electron, Transmission
  • Nanostructures / chemistry*
  • Oligopeptides / chemistry*
  • Phosphoserine / analogs & derivatives
  • Semiconductors*
  • Sulfides / chemistry*

Substances

  • Cadmium Compounds
  • Hydroxyapatites
  • Oligopeptides
  • Sulfides
  • cadmium sulfide
  • Phosphoserine
  • arginyl-glycyl-aspartic acid