Abstract
Reaction of [ReBr3(CO)3]2- with aryldiazonium salts gives the Re(iii) diazenide complexes [ReBr2(NNC6H4R-4)(CO)2]-. The attachment of a PhNHCS tethering group to pyridyl hydrazine generates a HYNIC related proligand which gives a stable chelated pyridyliumthiocarbazide(2-) derivative of the [Re(I)(CO)3]+ core.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Carbon Monoxide / chemistry
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Crystallography, X-Ray
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Hydrazines / chemistry*
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Molecular Structure
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Organomercury Compounds / chemistry
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Radioisotopes / chemistry
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Radiopharmaceuticals / chemistry
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Rhenium / chemistry*
Substances
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Hydrazines
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Organomercury Compounds
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Radioisotopes
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Radiopharmaceuticals
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Rhenium
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Carbon Monoxide