Abstract
A new indene-based ligand featuring pendant phosphine sulfide and amine donor fragments has been developed; Rh(I) coordinates to the neutral form of the ligand in a kappa2-[N,S] fashion, while the anionic form of the ligand binds Rh(I) and Mn(I) in kappa2-[C,S] and eta5 modes, respectively.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Crystallography, X-Ray
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Indenes / chemistry*
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Ligands
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Manganese / chemistry*
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis*
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Rhodium / chemistry*
Substances
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Indenes
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Ligands
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Organometallic Compounds
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Manganese
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Rhodium