Enhancement of alpha-oxygen formation and N2O decomposition on Fe/ZSM-5 catalysts by extraframework Al

Chem Commun (Camb). 2004 Nov 7:(21):2480-1. doi: 10.1039/b408854a. Epub 2004 Sep 16.

Abstract

The concentration of alpha-oxygen which can oxidize methane to methanol and benzene to phenol at RT, increases linearly with the amount of introduced extraframework Al on Fe/ZSM-5 catalysts prepared by solid-state exchange of FeCl3 and AlCl3 with H-ZSM-5.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aluminum Chloride
  • Aluminum Compounds / chemistry*
  • Catalysis
  • Chlorides / chemistry*
  • Ferric Compounds / chemistry*
  • Iron / chemistry*
  • Nitrous Oxide / chemistry*
  • Oxygen / chemistry*
  • Temperature
  • Zeolites / chemistry*

Substances

  • Aluminum Compounds
  • Chlorides
  • Ferric Compounds
  • Zeolites
  • Aluminum Chloride
  • Iron
  • Nitrous Oxide
  • Oxygen
  • ferric chloride