Abstract
Ammonium ylides generated in situ from [small alpha]-diazo esters and amines in the presence of catalytic Rh2(OAc)4, undergo an aldol-type reaction with aldehydes affording highly substituted amino acid frameworks in a convergent, three-component reaction.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Aldehydes / chemistry*
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Amino Acids / chemistry*
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Crystallography, X-Ray
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Models, Molecular
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Molecular Structure
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Quaternary Ammonium Compounds / chemical synthesis*
Substances
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Aldehydes
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Amino Acids
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Quaternary Ammonium Compounds