A comparison of the efficacy of a bispyridinium oxime--1,4-bis-(2-hydroxyiminomethylpyridinium) butane dibromide and currently used oximes to reactivate sarin, tabun or cyclosarin-inhibited acetylcholinesterase by in vitro methods

Pharmazie. 2004 Oct;59(10):795-8.

Abstract

The efficacy of a bispyridinium oxime 1,4-bis(2-hydroxyiminomethylpyridinium) butane dibromide, called K033, and of currently used oximes (pralidoxime, obidoxime, oxime HI-6), to reactivate acetylcholinesterase inhibited by various nerve agents (sarin, tabun cyclosarin) was tested by in vitro methods. The new oxime K033 was found to be a more efficacious reactivator of sarin or cyclosarin-inhibited acetylcholinesterase than pralidoxime and obidoxime but it did not reach the efficacy of oxime HI-6 in the case of the inhibition of acetylcholinesterase by sarin or cyclosarin. On the other hand, oxime K033 was more efficacious than oxime HI-6 in reactivating tabun-inhibited acetylcholinesterase. Thus, oxime K033 seems to be a relatively efficacious broad spectrum acetylcholinesterase reactivator and, therefore, could be useful if no information about the type of nerve agent used was available.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetylcholinesterase / chemistry
  • Acetylcholinesterase / metabolism*
  • Animals
  • Brain / drug effects
  • Brain / enzymology
  • Chemical Warfare Agents / pharmacology*
  • Cholinesterase Inhibitors / pharmacology*
  • Cholinesterase Reactivators / pharmacology*
  • Male
  • Obidoxime Chloride / pharmacology
  • Organophosphates / pharmacology*
  • Organophosphorus Compounds / pharmacology*
  • Oximes / pharmacology*
  • Pralidoxime Compounds / pharmacology
  • Pyridinium Compounds / pharmacology*
  • Rats
  • Rats, Wistar
  • Sarin / pharmacology*

Substances

  • 1,4-bis(2-hydroxyiminomethylpyridinium)butane
  • Chemical Warfare Agents
  • Cholinesterase Inhibitors
  • Cholinesterase Reactivators
  • Organophosphates
  • Organophosphorus Compounds
  • Oximes
  • Pralidoxime Compounds
  • Pyridinium Compounds
  • Obidoxime Chloride
  • Sarin
  • Acetylcholinesterase
  • asoxime chloride
  • pralidoxime
  • tabun
  • cyclohexyl methylphosphonofluoridate