Field-driven crossover from attractive-to-repulsive Casimir-like force in smectic films

Phys Rev E Stat Nonlin Soft Matter Phys. 2004 Nov;70(5 Pt 1):050702. doi: 10.1103/PhysRevE.70.050702. Epub 2004 Nov 30.

Abstract

External fields have a profound effect on the fluctuations of strongly correlated fluids, such as a liquid crystal. Within a harmonic functional integral approach, we compute the fluctuation-induced force between the surfaces of a smectic liquid-crystal film under the presence of an ordering field. In particular, we show that for asymmetrically anchored films, the thermal Casimir interaction energy can be collapsed into a universal form crossing over from a repulsive to an attractive interaction as the film thickness is increased. We discuss the possible relevance of this field effect in nematic-smectic wetting transitions.