Radiocarbon and stable carbon isotope compositions of chemically fractionated soil organic matter in a temperate-zone forest

J Environ Radioact. 2005;79(2):137-56. doi: 10.1016/j.jenvrad.2004.06.002.

Abstract

To better understand the role of soil organic matter in terrestrial carbon cycle, carbon isotope compositions in soil samples from a temperate-zone forest were measured for bulk, acid-insoluble and base-insoluble organic matter fractions separated by a chemical fractionation method. The measurements also made it possible to estimate indirectly radiocarbon ((14)C) abundances of acid- and base-soluble organic matter fractions, through a mass balance of carbon among the fractions. The depth profiles of (14)C abundances showed that (1) bomb-derived (14)C has penetrated the first 16cm mineral soil at least; (2) Delta(14)C values of acid-soluble organic matter fraction are considerably higher than those of other fractions; and (3) a significant amount of the bomb-derived (14)C has been preserved as the base-soluble organic matter around litter-mineral soil boundary. In contrast, no or little bomb-derived (14)C was observed for the base-insoluble fraction in all sampling depths, indicating that this recalcitrant fraction, accounting for approximately 15% of total carbon in this temperate-zone forest soil, plays a role as a long-term sink in the carbon cycle. These results suggest that bulk soil organic matter cannot provide a representative indicator as a source or a sink of carbon in soil, particularly on annual to decadal timescales.

MeSH terms

  • Carbon Isotopes / analysis*
  • Carbon Radioisotopes / analysis*
  • Organic Chemicals / chemistry*
  • Soil / analysis*
  • Soil Pollutants, Radioactive / analysis
  • Solubility
  • Temperature
  • Time Factors
  • Trees / metabolism*

Substances

  • Carbon Isotopes
  • Carbon Radioisotopes
  • Organic Chemicals
  • Soil
  • Soil Pollutants, Radioactive