A new high affinity technetium-99m-bombesin analogue with low abdominal accumulation

Bioconjug Chem. 2005 Jan-Feb;16(1):43-50. doi: 10.1021/bc049820h.

Abstract

99mTc-labeled bombesin analogues have shown promise for noninvasive detection of many tumors that express bombesin (BN)/gastrin-releasing peptide (GRP) receptors. 99mTc-labeled peptides, however, have a tendency to accumulate in the liver and intestines due to hepatobiliary clearance as a result of the lipophilicity of the 99mTc chelates. This makes the imaging of lesions in the abdominal area difficult. In this study, we have synthesized a new high affinity 99mTc-labeled BN analogue, [DTPA1, Lys3(99mTc-Pm-DADT), Tyr4]BN, having a built-in pharmacokinetic modifier, DTPA, and labeled with 99mTc using a hydrophilic diaminedithiol chelator (Pm-DADT) to effect low hepatobiliary clearance. In vitro binding studies using human prostate cancer PC-3 cell membranes showed that the inhibition constant (Ki) for [DTPA1, Lys3(99Tc-Pm-DADT), Tyr4]BN was 4.1 +/- 1.4 nM. Biodistribution studies of [DTPA1, Lys3(99mTc-Pm-DADT), Tyr4]BN in normal mice showed very low accumulation of radioactivity in the liver and intestines (1.32 +/- 0.13 and 4.58 +/- 0.50% ID, 4 h postinjection, respectively). There was significant uptake (7.71 +/- 1.37% ID/g, 1 h postinjection) in the pancreas which expresses BN/GRP receptors. The uptake in the pancreas could be blocked by BN, partially blocked by neuromedin B, but not affected by somatostatin, indicating that the in vivo binding was BN/GRP receptor specific. Scintigraphic images showed specific, high contrast delineation of prostate cancer PC-3 xenografts in SCID mice. Thus, the new peptide has a great potential for imaging BN/GRP receptor-positive cancers located even in the abdomen.

Publication types

  • Comparative Study
  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Abdomen / diagnostic imaging
  • Abdomen / physiology*
  • Animals
  • Binding Sites / drug effects
  • Bombesin / metabolism
  • Disease Models, Animal
  • Humans
  • Male
  • Mice
  • Neoplasm Transplantation
  • Neurokinin B / analogs & derivatives*
  • Neurokinin B / pharmacology
  • Prostatic Neoplasms / diagnostic imaging
  • Prostatic Neoplasms / metabolism
  • Radionuclide Imaging
  • Radiopharmaceuticals / metabolism*
  • Receptors, Bombesin / metabolism
  • Somatostatin / pharmacology
  • Technetium Tc 99m Sestamibi / metabolism*
  • Tissue Distribution
  • Tumor Cells, Cultured
  • Xenograft Model Antitumor Assays

Substances

  • Radiopharmaceuticals
  • Receptors, Bombesin
  • Somatostatin
  • Neurokinin B
  • neuromedin B
  • Technetium Tc 99m Sestamibi
  • Bombesin