Activated protein C, a natural anticoagulant protein, has antioxidant properties and inhibits lipid peroxidation and advanced glycation end products formation

Thromb Res. 2005;115(4):319-25. doi: 10.1016/j.thromres.2004.09.011.

Abstract

Introduction: Activated protein C (APC) is an important natural anticoagulant that is proteolytically generated from protein C (PC) by the modulation of thrombin activity in the presence of thrombomodulin on an endothelial surface. Recent studies have demonstrated that, beyond its anticoagulant acitivities, APC had anti-inflammatory and cytoprotective properties. The mechanisms underlying APC's anti-inflammatory effects remain unknown. Our goal was to elucidate and confirm these mechanisms.

Methods: We first examined the effect of APC on reactive oxygen species (ROS) and inflammatory cytokine production in murine macrophage-like RAW264.7 cells. We further examined the effect of APC on chemically induced lipid peroxidation and advanced glycation end-products (AGE) formation.

Results and conclusions: APC in the range of 10-50 microg/mL could reduce lipopolysaccharide (LPS)-induced ROS generation, nuclear factor kappaB (NF-kappaB) activation and resultant proinflammatory cytokine production. Additional cell-free experiments revealed that APC (10-50 microg/mL) had inhibitory effects on lipid peroxidation and AGE formation. These findings suggest that APC, via its intrinsic anti-oxidant properties, may, in settings of oxidant stress, exert important cytoprotective and anti-inflammatory effects that are distinct from its anticoagulant activity as an antioxidant protein. If that is true, APC may contribute to ROS-related chronic disorders including atherosclerosis and diabetes as well as acute shock conditions.

MeSH terms

  • Animals
  • Anticoagulants / metabolism*
  • Anticoagulants / pharmacology*
  • Antioxidants / metabolism*
  • Antioxidants / pharmacology*
  • Cell Line
  • Cell-Free System
  • Copper / pharmacology
  • Cytokines / biosynthesis
  • Glycation End Products, Advanced / biosynthesis*
  • Inflammation Mediators / metabolism
  • Interleukin-1 / biosynthesis
  • Lipid Peroxidation / drug effects*
  • Lipopolysaccharides / pharmacology
  • Lipoproteins, LDL / metabolism
  • Mice
  • NF-kappa B / metabolism
  • Protein C / metabolism*
  • Protein C / pharmacology*
  • Reactive Oxygen Species / metabolism
  • Tumor Necrosis Factor-alpha / biosynthesis

Substances

  • Anticoagulants
  • Antioxidants
  • Cytokines
  • Glycation End Products, Advanced
  • Inflammation Mediators
  • Interleukin-1
  • Lipopolysaccharides
  • Lipoproteins, LDL
  • NF-kappa B
  • Protein C
  • Reactive Oxygen Species
  • Tumor Necrosis Factor-alpha
  • Copper