Abstract
A highly stable porphyrin-fullerene conjugate with defined distance and orientation, was formed using a newly developed 'two-point' binding strategy involving axial-coordination and cation-crown ether complexation; photochemical studies performed in benzonitrile revealed efficient charge separation and slow charge-recombination in the supramolecular complex.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Binding Sites
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Cations / chemistry
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Crown Ethers / chemistry*
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Crystallography, X-Ray
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Fullerenes / chemistry*
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Hydrogen Bonding
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Macromolecular Substances / chemistry
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Magnetic Resonance Spectroscopy / methods
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
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Porphyrins / chemistry*
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Sensitivity and Specificity
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Zinc / chemistry*
Substances
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Cations
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Crown Ethers
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Fullerenes
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Macromolecular Substances
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Organometallic Compounds
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Porphyrins
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Zinc