Nickel catalysed asymmetric cycloisomerisation of diethyl diallylmalonate

Chem Commun (Camb). 2005 Mar 21:(11):1456-8. doi: 10.1039/b417333c. Epub 2005 Jan 25.

Abstract

Cationic nickel catalysts with monodentate phosphoramidites and Wilke's azaphospholene as ligands are highly regio- and enantioselective catalysts for the cycloisomerisation of diethyl diallylmalonate.

MeSH terms

  • Catalysis
  • Cyclization
  • Ligands
  • Malonates / chemistry*
  • Molecular Structure
  • Nickel / chemistry*
  • Organophosphorus Compounds / chemistry
  • Stereoisomerism

Substances

  • Ligands
  • Malonates
  • Organophosphorus Compounds
  • diethyl diallylmalonate
  • phosphoramidite
  • Nickel