Sorption and desorption of perchlorate and U(VI) by strong-base anion-exchange resins

Environ Sci Technol. 2005 Feb 1;39(3):901-7. doi: 10.1021/es049121f.

Abstract

This study investigated the sorption affinity and capacity of six strong-base anion-exchange (SBA) resins for both uranium [U(VI)] and perchlorate (ClO4-) in simulated groundwater containing varying concentrations of sulfate (SO4(2-)). Additionally, desorption of U(VI) from spent resins was studied to separate U(VI) from resins with sorbed ClO4- for waste segregation and minimization. Results indicate that all SBA resins investigated in this study strongly sorb U(VI). The gel-type polyacrylic resin (Purolite A850) showed the highest sorption affinity and capacityfor U(VI) butwasthe least effective in sorbing ClO4-. The presence of SO4(2-) had little impact on the sorption of U(VI) but significantly affected the sorption of ClO4-, particularly on monofunctional SBA resins. A dilute acid wash was found to be effective in desorbing U(VI) but ineffective in desorbing ClO4- from bifunctional resins (Purolite A530E and WBR109). A single wash removed approximately 75% of sorbed U(VI) but only approximately 0.1% of sorbed ClO4- from the bifunctional resins. On the other hand, only 21.4% of sorbed U(VI) but approximately 34% of sorbed ClO4- was desorbed from the Purolite A850 resin. This study concludes that bifunctional resins could be used effectively to treatwater contaminated with ClO4- and traces of U(VI), and dilute acid washes could minimize hazardous wastes by separating sorbed U(VI) from ClO4- prior to the regeneration of the spent resin loaded with ClO4-.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Anion Exchange Resins*
  • Hydrogen-Ion Concentration
  • Perchlorates / chemistry*
  • Perchlorates / isolation & purification*
  • Waste Disposal, Fluid
  • Water Pollutants, Chemical / isolation & purification*
  • Water Purification / methods

Substances

  • Anion Exchange Resins
  • Perchlorates
  • Water Pollutants, Chemical
  • perchlorate