Directed palladation: fine tuning permits the catalytic 2-alkenylation of indoles

Chem Commun (Camb). 2005 Apr 14:(14):1854-6. doi: 10.1039/b417035k. Epub 2005 Feb 17.

Abstract

A C-H activating Pd-catalysed alkenylation of indole is regiospecific for 2-substitution when the nitrogen carries a 2-pyridylmethyl substituent.