[Raman spectra of complexes of rare earth nitrate with histidine]

S Gao; M Ji; J Liu; Y Hou; S Chen

[Raman spectra of complexes of rare earth nitrate with histidine]

Guang Pu Xue Yu Guang Pu Fen Xi. 1999 Dec;19(6):814-6.

[Article in Chinese]

Authors

S Gao¹, M Ji, J Liu, Y Hou, S Chen

Affiliation

¹ Department of Chemistry, Northwest University, 710069 -Xi'an.

PMID: 15822305

Abstract

Raman spectra of solid complexes RE(His)(NO3)3 x H2O (RE = La-Nd, Sm-Lu, Y; His = L-alpha-histidine ) have been investigated. The results indicate that RE3+ coordinates with one O atome of carboxyl group in the complex, while amino group and imidazole ring do not take part in coordination and NO3 is double coordination. The vibration peaks of carboxyl group delta(v)COO-(as-s) were plotted against the atomic number of the lanthanoids, which obeys Oddo-Harkins law.

Publication types

English Abstract
Research Support, Non-U.S. Gov't

MeSH terms

Histidine / chemistry*
Metals, Rare Earth / chemistry*
Spectrum Analysis, Raman

Substances

Metals, Rare Earth
Histidine