Evaluation of photolyase (Photosome) repair activity in human keratinocytes after a single dose of ultraviolet B irradiation using the comet assay

J Photochem Photobiol B. 2005 May 13;79(2):101-8. doi: 10.1016/j.jphotobiol.2004.11.022. Epub 2005 Jan 22.

Abstract

Photosome is constituted of photolyases included in liposomes. Photolyase is a bacterial enzyme that can repair ultraviolet B (UVB)-induced cyclobutane pyrimidine dimers (CPD) in eukaryotic cells. A modified version of the alkaline comet assay has been set up to evaluate the repair activity of this enzyme after a single dose of UVB (312 nm, 0.06 J/cm2) in human keratinocytes. The formation of single strand breaks (SSB) induced by the UVA photoactivation of the enzyme (1.2 J/cm2) was inhibited by the pretreatment of the cells with 4 mM L-ergothioneine (ERT) during 30 min at 37 degrees C. To increase the sensitivity of the comet assay, an additional lysis was used with a buffer containing sodium dodecyl sulfate (0.5%) and proteinase K (0.1 mg/ml) for 60 min at 37 degrees C. Unrepaired CPD by photolyase were revealed by a second enzymatic treatment with T4 endonuclease V, a CPD specific glycosylase. UVB irradiation increased the SSB level in keratinocytes and additional T4NV treatment enhanced this SSB level by 1.5-2.0-fold confirming that CPD were the major base modifications generated by UVB irradiation. UVA-photoactivated Photosome repaired CPD lesions and decreased the SSB levels by 2.6-3.3-fold. Photosome could be an additional component of sunscreens to reduce the development of skin cancer.

MeSH terms

  • Cells, Cultured
  • Comet Assay*
  • Deoxyribodipyrimidine Photo-Lyase / metabolism*
  • Deoxyribonuclease (Pyrimidine Dimer) / metabolism
  • Endopeptidase K / metabolism
  • Ergothioneine / pharmacology
  • Humans
  • Keratinocytes / cytology
  • Keratinocytes / drug effects
  • Keratinocytes / enzymology*
  • Keratinocytes / radiation effects*
  • Sodium Dodecyl Sulfate / pharmacology
  • Ultraviolet Rays*
  • Viral Proteins / metabolism

Substances

  • Viral Proteins
  • Sodium Dodecyl Sulfate
  • Ergothioneine
  • endonuclease V, phage T4
  • Deoxyribonuclease (Pyrimidine Dimer)
  • Endopeptidase K
  • Deoxyribodipyrimidine Photo-Lyase