Directed library of anilinogeranyl analogues of farnesyl diphosphate via mixed solid- and solution-phase synthesis

Org Lett. 2005 May 26;7(11):2109-12. doi: 10.1021/ol050386o.

Abstract

[reaction: see text]. A directed library of anilinogeranyl diphosphate analogues of the isoprenoid farnesyl diphosphate has been prepared by solid-phase organic synthesis using a traceless linker strategy in moderate yield in three steps: reductive amination, bromination, and treatment with ((n-Bu)4N)3HP2O7.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Acyclic Monoterpenes
  • Alcohols / chemical synthesis
  • Alcohols / chemistry
  • Aniline Compounds / chemical synthesis*
  • Aniline Compounds / chemistry
  • Combinatorial Chemistry Techniques*
  • Molecular Structure
  • Polyisoprenyl Phosphates / chemical synthesis*
  • Polyisoprenyl Phosphates / chemistry
  • Sesquiterpenes
  • Terpenes / chemical synthesis*
  • Terpenes / chemistry

Substances

  • Acyclic Monoterpenes
  • Alcohols
  • Aniline Compounds
  • Polyisoprenyl Phosphates
  • Sesquiterpenes
  • Terpenes
  • farnesyl pyrophosphate
  • geraniol