Abstract
[reaction: see text] The first syntheses of peroxyacarnoates A and D, members of a family of enyne-containing alkoxydioxanes, have been achieved on the basis of chemoselective ozonolysis within a polyunsaturated framework and Pd-mediated cross-couplings of a functionalized 1,2-dioxane.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Alkenes / chemical synthesis*
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Alkenes / chemistry
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Animals
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Biological Products / chemical synthesis*
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Biological Products / chemistry
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Catalysis
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Dioxanes / chemical synthesis*
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Dioxanes / chemistry
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Indicators and Reagents
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Molecular Structure
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Palladium / chemistry
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Porifera / chemistry
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Stereoisomerism
Substances
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Alkenes
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Biological Products
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Dioxanes
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Indicators and Reagents
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peroxyacarnoate A
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peroxyacarnoate D
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Palladium