Borinium, borenium, and boronium ions: synthesis, reactivity, and applications

Angew Chem Int Ed Engl. 2005 Aug 12;44(32):5016-36. doi: 10.1002/anie.200500402.

Abstract

Boron cations are elusive and highly electrophilic species that play a key role in the chemistry of boron. Despite early interest in the chemistry of boron cations, until recently they have largely remained chemical curiosities. However, hints at harnessing their potential as potent electrophiles have begun to appear and developments in weakly coordinating anion technology suggest that this is an area of research that is ripe for exploration. It has been nearly 20 years since the last major review on boron cations; herein we summarize the progress in the area since that time.

Publication types

  • Review

MeSH terms

  • Boron Compounds* / chemical synthesis
  • Boron Compounds* / chemistry
  • Cations
  • Crystallography, X-Ray
  • Models, Molecular
  • Molecular Structure
  • Oxidation-Reduction
  • Stereoisomerism

Substances

  • Boron Compounds
  • Cations