Deracemization of quaternary stereocenters by Pd-catalyzed enantioconvergent decarboxylative allylation of racemic beta-ketoesters

Angew Chem Int Ed Engl. 2005 Oct 28;44(42):6924-7. doi: 10.1002/anie.200502018.
No abstract available

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkylation
  • Catalysis
  • Decarboxylation
  • Esters / chemical synthesis*
  • Ketones / chemical synthesis*
  • Molecular Structure
  • Organometallic Compounds / chemistry*
  • Palladium / chemistry*
  • Stereoisomerism

Substances

  • Esters
  • Ketones
  • Organometallic Compounds
  • Palladium