Acyl 1,3-migration in rhodium-catalyzed reactions of acetylenic beta-ketoesters with aryl boronic acids: application to two-carbon-atom ring expansions

Angew Chem Int Ed Engl. 2005 Nov 25;44(46):7598-600. doi: 10.1002/anie.200502650.
No abstract available

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetylation
  • Alkynes / chemistry*
  • Boronic Acids / chemistry*
  • Carbon / chemistry*
  • Catalysis
  • Esters / chemical synthesis*
  • Esters / chemistry
  • Hydrogen-Ion Concentration
  • Ketones / chemical synthesis*
  • Ketones / chemistry
  • Molecular Structure
  • Organometallic Compounds / chemistry*
  • Rhodium / chemistry*
  • Stereoisomerism

Substances

  • Alkynes
  • Boronic Acids
  • Esters
  • Ketones
  • Organometallic Compounds
  • Carbon
  • Rhodium