Synthesis and anti-HIV activity of bi-functional betulinic acid derivatives

Bioorg Med Chem. 2006 Apr 1;14(7):2279-89. doi: 10.1016/j.bmc.2005.11.016. Epub 2005 Nov 28.

Abstract

Betulinic acid (BA) derivatives with a side chain at C-3 can inhibit HIV-1 maturation. On the other hand, BA derivatives with a side chain at C-28 can block HIV-1 entry. In order to combine the anti-maturation and anti-entry activities in a single molecule, new bi-functional BA derivatives containing side chains at C-3 and C-28 have been synthesized. The most potent compound ([[N-[3beta-O-(3',3'-dimethylsuccinyl)-lup-20(29)-en-28-oyl]-7-aminoheptyl]-carbamoyl]methane) inhibited HIV-1 at an EC50 of 0.0026 microM and was at least 20 times more potent than either the anti-maturation lead compound DSB or the anti-entry lead compound IC9564. This bi-functional BA derivative was active against both HIV entry and maturation. These results suggest that bi-functional BA derivatives with dual mechanisms of action have the potential to become clinically useful for AIDS therapy.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Animals
  • Anti-HIV Agents / chemical synthesis*
  • Anti-HIV Agents / chemistry
  • Anti-HIV Agents / pharmacology*
  • Betulinic Acid
  • COS Cells
  • Cell Fusion
  • Chlorocebus aethiops
  • HIV-1 / drug effects*
  • Microbial Sensitivity Tests
  • Molecular Conformation
  • Pentacyclic Triterpenes
  • Triterpenes / chemical synthesis*
  • Triterpenes / chemistry
  • Triterpenes / pharmacology*

Substances

  • Anti-HIV Agents
  • Pentacyclic Triterpenes
  • Triterpenes
  • Betulinic Acid