Abstract
A quinine/Selectfluor combination inducing rearrangement reaction of allylic alcohols was discovered, which involved a moderate yield with good enantioselective construction of alpha-quaternary carbon center and beta-fluoro aldehyde under base condition.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Aldehydes / chemistry*
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Cyclohexenes / chemistry*
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Diazonium Compounds / chemistry*
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Fluorine / chemistry*
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Molecular Structure
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Propanols / chemistry*
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Quinine / chemistry*
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Stereoisomerism
Substances
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Aldehydes
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Cyclohexenes
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Diazonium Compounds
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Propanols
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semipinacol
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Fluorine
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allyl alcohol
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selectfluor
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Quinine