A facile method to prepare heparin-functionalized nanoparticles for controlled release of growth factors

Biomaterials. 2006 Apr;27(12):2621-6. doi: 10.1016/j.biomaterials.2005.11.043. Epub 2005 Dec 19.

Abstract

A new, facile method to prepare the heparin-functionalized PLGA nanoparticle (HEP-PLGA NP) for the controlled release of growth factors is developed. This system is composed of PLGA as a hydrophobic core, Pluronic F-127 as a hydrophilic surface layer, and heparin as the functional moiety. HEP-PLGA NPs were prepared by a solvent-diffusion method without chemical modification of the components. The entrapment of heparin molecules was confirmed by a negatively increased zeta potential value and the specific binding affinity to antithrombin III. The average diameter and the surface charge of the nanoparticles were ranged from 139+/-2 to 188+/-4 nm and from -26.0+/-1.1 to -44.1+/-1.3 mV by increasing the amount of heparin during the nanoparticle preparation. Accordingly, the amount of heparin on the nanoparticle increased from 0% to 4.7%. As a model in vitro release experiment, lysozyme was loaded into HEP-PLGA NPs, and a sustained release profile over 2 weeks was obtained with maintaining its bioactivity. The release of rhVEGF, one of the heparin-binding growth factors, showed a more sustained and prolonged profile than that of lysozyme over one month.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biocompatible Materials / chemistry*
  • Biocompatible Materials / metabolism
  • Drug Carriers / chemistry*
  • Drug Carriers / metabolism
  • Growth Substances / metabolism*
  • Heparin / analogs & derivatives*
  • Heparin / chemistry
  • Heparin / metabolism
  • Humans
  • Lactic Acid / chemistry*
  • Lactic Acid / metabolism
  • Materials Testing
  • Muramidase / metabolism
  • Particle Size
  • Polyglycolic Acid / chemistry*
  • Polyglycolic Acid / metabolism
  • Polylactic Acid-Polyglycolic Acid Copolymer
  • Polymers / chemistry*
  • Polymers / metabolism
  • Vascular Endothelial Growth Factor A / metabolism

Substances

  • Biocompatible Materials
  • Drug Carriers
  • Growth Substances
  • Polymers
  • Vascular Endothelial Growth Factor A
  • Polylactic Acid-Polyglycolic Acid Copolymer
  • Polyglycolic Acid
  • Lactic Acid
  • Heparin
  • Muramidase