Protein sites of attack of N-chlorotaurine in Escherichia coli

Proteomics. 2006 Feb;6(3):865-9. doi: 10.1002/pmic.200500054.

Abstract

N-Chlorotaurine sodium (NCT) is a promising microbicidal agent for topical treatment of infections. Its targets of attack in Escherichia coli have been investigated by proteomics. Incubation in 1% NCT for 10 and 30 min revealed a change of the charge and a separation of numerous proteins into a series of spots with a different pI. Charge differences could be related to oxidation of cysteine residues to their corresponding sulfonic acids. Heat shock protein 60 appeared, while ribosome-releasing factor, d-ribose periplasmic binding protein, and malonyl-CoA transacylase spots decreased. These results indicate penetration of oxidation capacity into the bacteria and destruction of essential proteins by NCT.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acyl-Carrier Protein S-Malonyltransferase / metabolism
  • Bacterial Proteins / drug effects
  • Chaperonin 60 / metabolism
  • Cysteine / chemistry
  • Electrophoresis, Gel, Two-Dimensional
  • Enzyme Inhibitors / pharmacology*
  • Escherichia coli / drug effects*
  • Escherichia coli / metabolism*
  • Oxidation-Reduction
  • Periplasmic Binding Proteins / metabolism
  • Protein Serine-Threonine Kinases / antagonists & inhibitors*
  • Proteomics*
  • Ribosomal Proteins / metabolism
  • Spectrometry, Mass, Electrospray Ionization
  • Sulfonic Acids / metabolism
  • Taurine / analogs & derivatives*
  • Taurine / pharmacology

Substances

  • Bacterial Proteins
  • Chaperonin 60
  • Enzyme Inhibitors
  • Periplasmic Binding Proteins
  • Ribosomal Proteins
  • Sulfonic Acids
  • ribosome releasing factor
  • Taurine
  • N-chlorotaurine
  • Acyl-Carrier Protein S-Malonyltransferase
  • Protein Serine-Threonine Kinases
  • Cysteine