Study on the synthesis of poly(diglycidyl maleate-co-stearyl methacrylate) and morphology conversion of their self-assembly systems

Haojie Yu; Li Wang; Junfeng Zhou; Guohua Jiang; Zhenrong Zhao

doi:10.1021/jp055557l

Study on the synthesis of poly(diglycidyl maleate-co-stearyl methacrylate) and morphology conversion of their self-assembly systems

J Phys Chem B. 2006 Jan 19;110(2):837-41. doi: 10.1021/jp055557l.

Authors

Haojie Yu¹, Li Wang, Junfeng Zhou, Guohua Jiang, Zhenrong Zhao

Affiliation

¹ State Key Laboratory of Polymer Reaction Engineering, College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China.

PMID: 16471612
DOI: 10.1021/jp055557l

Abstract

A novel polymer of poly(diglycidyl maleate-co-stearyl methacrylate) (P(DGMA-co-SMA)) was synthesized by reaction between poly(maleic anhydride-co-stearyl methacrylate) (P(MA-co-SMA)) and epichlorohydrin. The self-assembly behavior of the resultant copolymer was investigated. It was found that the spheral aggregates could converse to nanorods after being aged for 2.5 days and nanolines composed of the nanorods were obtained after being aged for an additional 5.5 days. The mechanism of their self-assembly behavior and morphology conversion of self-assembly systems is discussed.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Magnetic Resonance Spectroscopy
Polymers / chemistry*
Polymethacrylic Acids / chemical synthesis*
Polymethacrylic Acids / chemistry

Substances

Polymers
Polymethacrylic Acids
poly(diglycidyl maleate-co-stearyl methacrylate)